The Sunderland ace was adjudged the Top scorer and Most Valuable Player in the senior national team category.
Gyan played a key role in Ghana's qualification last year to the 2012 Africa Cup of Nations which was co-hosted by Gabon and Equatorial Guinea.
The 26-year-old has emerged as a key player of the Black Stars but asked for a temporary break from international football in February.
He piped former first choice goalkeeper Richard Kingson who made five Nations Cup finals appearances.
The 31-year-old quit international football after the 2010 FIFA World Cup finals in South Africa.
Appiah made 69 appearances for Ghana between 1996 and 2010 and scored 16 goals.
The midfielder revived his club career last season at Serbian top-flight side FK Vojvodina where he made 11 appearances and scored 1 goal in return.
Striker Richmond Boakye-Yiadom also bagged a double in the Black Satellites’ Division.
He came away with the Top Scorer and Most Valuable Player Awards while Rashid Sumaila picked up the Most Dedicated Player Award in that Division.
The National Player Awards is organized by the Retired National Footballers Association of Ghana and supported by the Ghana FA to award past and present international footballers.
E.E De Graft
1963 Ghana Squad
1965 Ghana squad
1978 Ghana squad
1982 Ghana squad
Most Valuable Player: Isaac Afoakwah
Most Dedicated: Abdul Baba Rahman
Top Scorer: Nasiru Mohammed
Most Valuable Player: Richmond Boakye-Yiadom
Most Dedicated: Sumaila Rashid
Top scorer: Richmond Boakye-Yiadom
Most Valuable Player: Richard Mpong
Most Dedicated: Daniel Agyei
Top scorer: Mahatma Otoo
Most Valuable Player: Asamoah Gyan
Most Dedicated: Stephen Appiah
Top scorer: Asamoah Gyan
Most Valuable Player: Beatrice Sesu
Most Dedicated: Cynthia Boakye-Yiadom
Top scorer: Rita Okyere
Most Valuable Player: Mercy Myles
Most Dedicated: Portia Boakye
Top scorer: Elizabeth Cudjoe
Most Valuable Player: Portia Boakye
Most Dedicated: Florence Okoe
Top scorer: Agnes Aduako
GHANA FA / GHANA WEB / MTN